个人介绍

1997.7毕业于西安交通大学，获高分子专业学士学位；

2000.7毕业于中国科学院化学研究所，获物理化学硕士学位；

2003.7毕业于中国科学院化学研究所，获物理化学博士学位。

2003.10-2007.5于美国哈佛大学从事博士后研究，主要方向为利用囚禁团簇离子电子衍射方法测量微观团簇结构；

2007.8-2009.10于美国华盛顿州立大学/太平洋西北国家实验室从事多电荷阴离子光电子速度成像研究。

2010.3-2013.9任中国科学院大学（原中国科学院研究生院）材料与光电技术学院副教授；

2013.10-2016.12任77779193永利副教授；

2017.1起任77779193永利教授。

一、研究方向

1.气相原子团簇物理化学

2.团簇束流源技术

3.飞行时间质谱、离子阱相关软/硬件技术

二、主要科研项目（建议列出重大研究课题、重点基金和在研课题）：

1.基金委青年基金项目(2012-2014)：气相金团簇离子与CO/O2 作用的动力学研究

2.基金委面上基金项目(2013-2016)：铂族金属与载体类氧化物复合团簇离子结构和反应特性的研究

3.基金委面上基金项目(2017-2020)：IB族金属团簇离子(0 - 1 nm)与CO、O2、NO的反应：利用动力学测量拟合结合能数值

4.部级特殊专项主题项目(2022-2024)

5.基金委面上基金项目(2023-2026)：金团簇键合单个掺杂原子的化学性质研究及其周期分析

6.基金委团簇重大专项集成项目子项目 (2025-2027)：金属团簇谱学数据集的构建与应用(团簇束流源相关技术)

三、学术成果

本课题组建设一套用于宽尺寸范围金属团簇化学反应性研究实验装置，包含了能够产生几个原子到纳米尺寸金属团簇的离子源、可控温的连续流动管反应器、以及高频的飞行时间质谱仪。此装置能够准确表征宽尺寸范围各类金属、半导体团簇离子的化学反应性质，辅助以量子化学计算、离子红外光解离谱、光电子谱等数据，可揭示宽尺寸范围原子团簇化学性质与几何、电子结构间的构效关系。

先前研究揭示了纯IB族金属团簇和O2、NO等小分子间化学反应性与团簇电子结构间的紧密关联；揭示了金属原子或非金属原子掺杂IB族金属团簇对其化学反应性的调控机制；最近发现了一个具有特殊几何及电子结构的具有显著惰性的开壳层团簇Bi18-，其独特结构为构筑稳定Bi基纳米结构提供了重要信息。

代表性论著：

46. Huang, L. L.; Liu, W.;Xing, X. P.,*Decomposition of Au_nO^-Clusters into Gold Oxide and Metallic Components: Unraveling the Impact of Single-Atom Oxygen on the Reactivity Modulation.Journal of Chemical Physics 2025,163, 064307.

45. Hu, X. T.; Liu, W.;Xing, X. P.,*An Innovative Inter-Spectral Distance-Based Approach toAnalyzing MALDI-TOF Mass Spectra of Closely Related Microbial Species.Rapid Communicationsin Mass Spectrometry 2025, 39, e10121.

44. Zou, G. P.; Huang, L. L.; Liu, W.; Hu, J.;Xing, X. P.,*Silicon Dopants Create Unique Active Sites on Gold Clusters toward Reactions with O₂.Journal of Physical Chemistry C 2025,129, 1206-1215.

43. Qiao, Z. Y.;* Hu, J.; Du, Q. Y.; Li, L.;Xing, X. P.;*Cao, Y. J.;* Zhao, J. J.,* Superatomic 1s Orbital-Mediated Ethylene Activation on Ag_n^-Clusters.Journal of Chemical Physics 2025,163,094305.

42. Ma, J.; Chen, T.T.;* Li, H. L.; Bumüller, D.; Weigend, F.; Jian, T.; Kappes, M. M.; Schooss, D.;* Li, W. L.;*Xing X. P.;*Wang L. S.,* On the remarkable resistance to oxidation by the Bi18- cluster.Science Advances 2024,10, eads4724.

41. Hu, J.;Xing, X. P.;*Wang, X. F.,* A Coppoborylene Stabilized by Multicenter Covalent Bonding and Its Amphoteric Reactivity to CO.Angewandte Chemie-International Edition 2024,63, e20240375.

40. Du, Q. Y.; Luo, Z. X.;*Xing, X. P.;*Zhao, J. J.,* Gas Phase Reactions of Pristine and Single-Atom-Doped Copper and Silver Clusters: Probing Size-Dependent Stability and Novel Superatoms.Journal of Physical Chemistry Letters 2024,15, 11383-11394.

39. Hu, J.; Huang, L. L.; Liu, W.; Jin, Z. Q.; Wang, X. F.;*Xing, X. P.,*Adsorption of O₂on Cationic Gold Clusters: Analyses on Bonding Strength and Extent of Activation.Chinese Journal of Chemical Physics 2024,37, 351-360.

38. Hu, J.; Ma, J.; Jin, Z. Q.; Liu, W.; Huang, L. L.; Wang, X. F.;*Xing, X. P.,*Reactivity of Cationic Silver Clusters with O₂: A Probe of Interplay between Clusters' Geometric and Electronic Structures.Physical Chemistry Chemical Physics 2024,26, 7407-7415.

37. Huang, L. L.; Liu, W.;Xing, X. P.,*Adsorption of O₂on the Preferred -O-Au Sites of Small Gold Oxide Clusters: Charge-Dependent Interaction and Activation.Molecules 2024,29, 1645.

36. Liu, W.; Huang, L. L.; Hu, J.;Xing, X. P.,*Adsorption of Multiple NO Molecules on Anionic Gold Clusters: Electron Transfer and Disproportionation Enhanced by Molecular Aggregation.Journal of Physical Chemistry A 2024,128, 4297-4307.

35. Hu, J.;Xing, X. P.;*Wang, X. F.,* Formation of Delocalized Linear M-B-M Covalent Bonds: A Combined Experimental and Theoretical Study of BM₂(CO)₈⁺(M = Co, Rh, Ir) Complexes.Inorganic Chemistry 2024,63, 13459-13467.

34. Han, C. C.; Liu, W.; Huang, L. L.; Xiong, X. G.; Dong, C. W.;*Xing, X. P.;*Liu, H. T., Probing the Geometric and Electronic Structure of Rhodium Oxide Clusters (RhO)_n^-(n= 2-4) by Anion Photoelectron Spectroscopy and Theoretical Calculations.Journal of Molecular Structure 2024,1318.

33. Hu, J.; Xin, K.; Lin, X.;Xing, X. P.;*Wang, X. F.,* Infrared Photodissociation Spectroscopy of Mass-Selected Dinuclear Transition Metal Boride Carbonyl Cluster Cations.Journal of Physical Chemistry A 2024,128, 2049-2057.

32. Du, Q. Y.; Huang, L. L.; Fu, J. Q.; Cao, Y. J.;Xing, X. P.;*Zhao, J. J.,* Single Atom Alloy Clusters Ag_n-1X^-(X = Cu, Au;n= 7-20) Reacting with O₂: Symmetry-Adapted Orbital Model.Journal of Chemical Physics 2023,158, 014306.

31. Liu, W.; Huang, L. L.; Meng, L.; Hu, J.;Xing, X. P.,*The Global Minimum of Ag₃₀: A Prolate Spheroidal Structure Predicted Using a Genetic Algorithm with Incomplete Local Optimizations at the DFT Level.Physical Chemistry Chemical Physics 2023,25, 14303-14310.

31. Huang, L. L.; Liu, W.; Hu, J.;Xing, X. P.,*Adsorption and Activation of O₂on Small Gold Oxide Clusters: The Reactivity Dominated by Site-Specific Factors.Journal of Physical Chemistry A 2022,126, 5594-5603.

30. Liu, W.; Huang, L. L.; Hu, J.;Xing, X. P.,*Various Bond Interactions between NO and Anionic Gold Clusters: A Theoretical Calculation.Physical Chemistry Chemical Physics 2022,24, 13641-13650.

29. Zhou, Y. Y.; Liu, H.; Jin, X. Y.;Xing, X. P.;*Wang, X. F.; Wang, G. J.;Zhou, M. F.,*Significant Π Bonding in Coinage Metal Complexes OC-TM-CCO^-from Infrared Photodissociation Spectroscopy and Theoretical Calculations.Journal of Chemical Physics 2022,157, 014302.

28. Du, Q. Y.; Hu, J.;Xing, X. P.;*Zhou, S.;* Zhao, J. J.,* Single O Atom Doped Ag Cluster Cations for CO Oxidation: An O-Doped Superatom Ag₁₅O⁺with Remarkable Stability.Journal of Physical Chemistry C 2021,125, 7067-7076.

27. Huang, L. L.; Liu, W.; Hu, J.;Xing, X. P.,*Exploring the Effects of a Doping Silver Atom on Anionic Gold Clusters' Reactivity with O₂.Journal of Physical Chemistry A 2021,125, 9995-10005.

26. Ma, J.; Wang, T. T.; Yang, J. J.; Hu, J.;Xing, X. P.,*Adsorption and Reactions of NO Molecules on Anionic Gold Clusters in the Size Range Below 1 nm: Effects of Clusters' Global Electronic Properties.Physical Chemistry Chemical Physics 2020,22, 25227-25235.

25. Yin, B. Q.; Wang, T. T.; Chen, Y. J.; Yang, J. J.; Wang, G. J.;Xing, X. P.,*Cooperative Bonding Interactions of Various Oxygen Species on the IB Group Metal Anions.International Journal of Mass Spectrometry 2020,451. 116312.

24. Wang, T. T.; Ma, J.; Yin, B. Q.;Xing, X. P.,*Adsorption of O₂on Anionic Gold Clusters in the 0-1 nm Size Range: An Insight into the Electron Transfer Dynamics from Kinetic Measurements.Journal of Physical Chemistry A 2018,122, 3346-3352.

23. Cao, X. Z.; Chen, M. Y.; Ma, J.; Yin, B. Q.;Xing, X. P.,*CO Oxidation by the Atomic Oxygen on Silver Clusters: Structurally Dependent Mechanisms Generating Free or Chemically Bonded CO₂.Physical Chemistry Chemical Physics 2017,19, 196-203.

22. Cao, X. Z.; Yin, B. Q.; Wang, T. T.;Xing, X. P.,*Exploring the Interactions of Atomic Oxygen on Silver Clusters with Hydrogen.Chinese Journal of Chemical Physics 2017,30, 685-690.

21. Ma, J.; Cao, X. Z.; Chen, M. Y.; Yin, B. Q.;Xing, X. P.;*Wang, X. F., Low-Temperature Disproportionation Reaction of NO on Au₆^-: A Mechanism Involving Three NO Molecules Promoted by the Negative Charge.Journal of Physical Chemistry A 2016,120, 9131-9137.

20. Wang, J.; Yan, Q. B.; Ma, J.; Cao, X. Z.;Xing, X. P.;* Wang, X. F. Exploring the low-lying structures of Au_n(CO)⁺(n= 1-10): adsorption and stretching frequencies of CO on various coordination sites.Rsc Advances 2016, 6, 8248-8255.

19. Ma, J.; Cao, X. Z.;Xing, X. P.;* Wang, X. F.; Parks, J. H. Adsorption of O₂on anionic silver clusters: spins and electron binding energies dominate in the range up to nano sizes.Physical Chemistry Chemical Physics 2016,18, 743-748.

18. Ma, J.; Cao, X. Z.; Liu, H.; Yin, B. Q.;Xing, X. P.* The adsorption and activation of NO on silver clusters with sizes up to one nanometer: interactions dominated by electron transfer from silver to NO.Physical Chemistry Chemical Physics 2016,18, 12819-12827.

17. Liu, H.;Xing, X. P.;* Wang, X. F.; Qu, H.; Wang, G. J.; Zhou, M. F.* Co-Adsorption of O₂and CO on Au₂^-: Infrared Photodissociation Spectroscopy and Theoretical Study of Au₂O₂(CO)_n^-(n= 2-6).Chemistry-A European Journal 2016, 22, 2085-2091.

16.Xing, X. P.; Li, X.; Yoon, B.; Landman, U.;* Parks, J. H.* Dynamic fluxionality and enhanced CO adsorption in the presence of coadsorbed H₂O on free gold cluster cations.International Journal of Mass Spectrometry 2015, 377, 393-402.

15. Xie, H.; Liu, Z. L.;Xing, X. P.;*Tang, Z. C.* Infrared photodissociation spectroscopy of MO(CO)₅⁺(M = Sc, Y, La and Ce) in the gas phase.Chemical Physics Letters 2015, 628, 66-70.

14. Liu, X.;Xing, X. P.;* Zhao, J.; Wang, X. F.* Reactions of Mg and Mg₂with SO₂in Low-Temperature Matrices: Association or Insertion?Journal of Physical Chemistry A 2015,119, 610-619.

13. Xie, H.; Wang, J.; Qin, Z. B.; Shi, L.; Tang, Z. C.;*Xing, X. P.* Octacoordinate Metal Carbonyls of Lanthanum and Cerium: Experimental Observation and Theoretical Calculation.Journal of Physical Chemistry A 2014,118, 9380-9385.

12.Xing, X. P.; Wang, G. J.; Wang, C. X.; Zhou, M. F. Infrared Photodissociation Spectroscopy of Ti⁺(CO₂)₂Ar and Ti⁺(CO₂)_n(n= 3-7) Complexes.Chinese Journal of Chemical Physics 2013, 26, 687-693.

Selected works before joining Tongji

11. Zhao, L. J.; Xie, H.; Liu, Z. L.; Wang, J.;Xing, X. P.;* Tang, Z. C.* Structure and Bonding in MPb₅^-(M = Cu, Ag, and Au): A Combined Investigation by Theoretical Calculations and Photoelectron Imaging Spectroscopy.Journal of Physical Chemistry A 2013,117, 2325-2332.

10.Xing, X. P.; Wang, J.; Xie, H.; Liu, Z. L.; Qin, Z. B.; Zhao, L. J.; Tang, Z. C.* Octacoordinate metal carbonyls of scandium and yttrium: theoretical calculations and experimental observation.Rapid Communications in Mass Spectrometry 2013, 27, 1403-1409.

9. Xie, H.; Li, X. Y.; Zhao, L. J.; Liu, Z. L.; Qin, Z. B.; Wu, X.; Tang, Z. C.;*Xing, X. P.* Vibrationally Resolved Photoelectron Imaging of Cu₂H^-and AgCuH^-and Theoretical Calculations.Journal of Physical Chemistry A 2013,117, 1706-1711.

8. Xie, H.; Li, X. Y.; Zhao, L. J.; Qin, Z. B.; Wu, X.; Tang, Z. C.;*Xing, X. P.* PhotoelectronImaging and Theoretical Calculations of Bimetallic Clusters: AgCu^-, AgCu₂^-, and Ag₂Cu^-.Journal of Physical Chemistry A 2012,116, 10365-10370.

7.Xing, X. P.; Wang, X. B.; Wang, L. S.* Photoelectron Imaging of Doubly Charged Anions,^-O₂C(CH₂)_nCO₂^-(n= 2-8): Observation of Near 0 eV Electrons Due to Secondary Dissociative Autodetachment.Journal of Physical Chemistry A 2010,114, 4524-4530.

6.Xing, X. P.; Wang, X.B.; Wang, L. S.* Photoelectron Angular Distribution and Molecular Structure in Multiply Charged Anions,Journal of Physical Chemistry A 2009, 113, 945-948. (Cover)

5.Xing, X. P.; Wang, X. B.; Wang, L. S.* Photoelectron Imaging of Multiply Charged Anions: Effects of Intramolecular Coulomb Repulsion and Photoelectron Kinetic Energies on Photoelectron Angular Distributions,Journal of Chemical Physics 2009, 130, 074301.

4.Xing, X. P.; Wang, X. B.; Wang, L. S.* Imaging Intramolecular Coulomb Repulsions in Multiply Charged Anions,Physical Review Letters 2008, 101, 083003.

3. J. H. Parks,X. P. Xing（2007）“Trapped Ion Electron Diffraction: Structural Evolution of Silver and Gold Clusters” in The Chemical Physics of Solid Surfaces Volume 12: Atomic Clusters: from Gas Phase to Deposited, D. P. Woodruff (Ed.) Elsevier, New York

2.Xing, X. P.; Yoon, B.; Landman, U.;* Parks, J. H.* Structural Evolution of Au Nanoclusters: From Planar to Cage to Tubular Motifs,Physical Review B 2006, 74, 165423.

1.Xing, X. P.; Danell, R. M.; Garzon, I. L.; Michaelian, K.; Blom, M. N.; Burns, M. M.; Parks, J. H.* Size-Dependent Fivefold and Icosahedral Symmetry in Silver Clusters,Physical Review B 2005, 72, 081405.(Rapid Communication)

本课题组热诚欢迎具有物理、化学、仪器等领域学习和工作背景，思维活跃的本科生联系攻读硕士研究生、直博研究生。